|
|
H2O + L-2-amino-4-chloro-4-pentenoate <=> 2-oxopent-4-enoate + NH3 + Cl- + H+
|
4.5.1.4
L-2-amino-4-chloropent-4-enoate dehydrochlorinase
|
–
|
|
|
BRENDA:
BR48364
KEGG:
R02605
MetaCyc:
4.5.1.4-RXN
|
|
|
|
2-hydroxy-2,4-pentadienoate <=> 2-oxopent-4-enoate
|
5.3.2.6
2-hydroxymuconate tautomerase
|
–
|
M
|
|
BRENDA:
BS422404
MetaCyc:
RXN-19492
SABIO-RK:
13517;
14758
|
|
|
|
2,6-dioxo-6-phenylhexa-3-enoate + H2O <=> benzoate + 2-oxopent-4-enoate
|
3.7.1.8
2,6-dioxo-6-phenylhexa-3-enoate hydrolase
|
–
|
K
|
|
BRENDA:
BR26139;
BS165546;
BS387151;
BS387152
KEGG:
R02606
SABIO-RK:
2512
|
|
|
|
2-hydroxymuconate-6-semialdehyde + H2O <=> formate + 2-oxopent-4-enoate
|
3.7.1.9
2-hydroxymuconate-6-semialdehyde hydrolase
|
–
|
BK
|
|
BRENDA:
BR26140
KEGG:
R02604
|
|
|
|
4-oxalocrotonate <=> 2-oxopent-4-enoate + CO2
|
4.1.1.77
2-oxo-3-hexenedioate decarboxylase
|
–
|
BK
|
|
BRENDA:
BS1617
KEGG:
R02602
|
|
|
|
2-hydroxy-6-oxo-6-(2-hydroxyphenyl)hexa-2,4-dienoate + H2O <=> 2-oxopent-4-enoate + salicylate
|
3.7.1
3.7.1.8
2,6-dioxo-6-phenylhexa-3-enoate hydrolase
|
–
–
|
K
|
|
BRENDA:
BS165545
KEGG:
R05360
|
|
|
|
4-hydroxy-2-oxopentanoate <=> 2-oxopent-4-enoate + H2O
|
4.2.1.80
2-oxopent-4-enoate hydratase
|
–
|
K
|
|
BRENDA:
BS363305;
BS378380
KEGG:
R02601
SABIO-RK:
2507
|
|
|
|
2-oxopent-4-enoate <=> (2Z)-2-hydroxypenta-2,4-dienoate
|
5.3.2.M1
|
–
|
M
|
|
MetaCyc:
RXN-7282
|
|
|
|
5-hydroxy-2-oxopentanoate <=> 2-oxopent-4-enoate + H2O
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-9168
|
|
|
|
2-oxopent-4-enoate + acceptor <=> 2-oxopenta-3,4-dienoate + reduced_acceptor
|
1
|
–
|
M
|
|
MetaCyc:
RXN-9169
|
|
|
|
2-hydroxy-6-oxo-6-(2,3-dihydroxyphenyl)-hexa-2,4-dienoate + H2O <=> 2,3-Dihydroxybenzoate + 2-oxopent-4-enoate + H+
|
3.7.1.8
2,6-dioxo-6-phenylhexa-3-enoate hydrolase
|
–
|
|
|
BRENDA:
BS422406
|
|
|
|
2-hydroxy-6-oxohepta-2,4-dienoate + H2O <=> formate + 2-oxopent-4-enoate
|
3.7.1.9
2-hydroxymuconate-6-semialdehyde hydrolase
|
–
|
|
|
BRENDA:
BS432593
|
|
|
|
allylglycine + H2O + NAD+ <=> 2-oxopent-4-enoate + NH3 + NADH
|
1.4.1.1
alanine dehydrogenase
|
–
|
|
|
BRENDA:
BS441495
|
|
|
|
2-oxo-3-hexenedioate <=> 2-oxopent-4-enoate + CO2
|
4.1.1.77
2-oxo-3-hexenedioate decarboxylase
|
–
|
B
|
|
BRENDA:
BR338
|
|